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2019, 05, v.38;No.167 337-346
共价有机框架材料研究进展
基金项目(Foundation): 江西省主要学科学术和技术带头人资助计划项目(2017BCB22020)
邮箱(Email):
DOI: 10.13355/j.cnki.sfyj.2019.05.001
摘要:

共价有机框架(COF)材料是通过自下而上方法合成的结晶多孔聚合物,其共价键连接的分子构建单元可在二级和三级结构上实现预先设计,能够合成高度有序的刚性多孔结构,并能够微调其化学和物理性质。这种材料在气体储存、分离、传感、电化学能量存储、光电子学、催化和放射性元素吸附治理等领域都有可观应用前景。概述了共价有机框架材料的结构,讨论了不同合成方法的结晶度、成膜条件,并展望了其未来的发展前景。

Abstract:

Covalent organic frameworks(COFs) materials are crystalline porous polymers formed by a bottom-up approach from molecular building units.The covalent bonds offer positional control over their predesigned building blocks in two-and three-dimensions.The control makes the synthesis have rigid porous structures with the ability to fine-tune the chemical and physical properties.The COFs can be applied in gas storage and separations,sensing,electrochemical energy storage,optoelectronic,catalysis and radioactive element adsorption.The paper summarizes the structure of covalent organic frameworks materials,and discusses the materials crystallinity prepared by different synthetic methods and film formation conditions.The future development of COFs materials is prospected.

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基本信息:

DOI:10.13355/j.cnki.sfyj.2019.05.001

中图分类号:O641.4

引用信息:

[1]余杰皓,刘峙嵘.共价有机框架材料研究进展[J].湿法冶金,2019,38(05):337-346.DOI:10.13355/j.cnki.sfyj.2019.05.001.

基金信息:

江西省主要学科学术和技术带头人资助计划项目(2017BCB22020)

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