1,288 | 97 | 86 |
下载次数 | 被引频次 | 阅读次数 |
我国钒矿资源,尤其是石煤资源储量丰富。统计表明:我国钒矿资源保有储量(以V2O5计)约3400万t,累计查明资源储量约3600万t,主要分布在四川、陕西、湖南、安徽、湖北等地,5省合计储量占全国的90.1%,累计查明储量占全国的88.9%。含钒石煤是我国一种独特的钒矿资源,其中V2O5储量约1128万t,占钒矿资源总储量的37.0%,主要分布在湖南、湖北、浙江、贵州等地,其中有工业开采价值的(w(V2O5)>0.8%)石煤中钒储量占62.6%。含钒石煤是我国钒矿资源利用的一个重要发展方向,本文综述了火法-湿法联用、湿法从石煤中提取钒的工艺以及存在的问题,对生物浸出钒及其它有价金属前景进行了展望。
Abstract:The reserves of vanadium resources,especially stone coal resources are abundant in China.Based on the statistical data,the available reserves of vanadium pentoxide resources are about 34 million tons,while accumulative total reserves are about 36 million tons,which are mainly distributed in provinces of Sichuan,Shanxi,Hu'nan,Anhui and Hubei.The available reserves and accumulative total proven reserves in above provinces account for 90.1% and 88.9% of the whole reserves in China,respectively.The stone coal is a special vanadium ore in China which reserves of V2O5 are about 11 million tons and account for 37.0% of the whole stone coal vanadium reserves,which are mainly distributed in provinces of Hu'nan,Hubei,Zhejiang and Guizhou.The available vanadium reserves in stone coal account for 62.6% which have industrial prospect and the content of V2O5 in these stone coal is more than 0.8%.Finally,main vanadium extraction processes by pydro-hydrometallurgy and hydrometallurgy are reviewed and some problems are also discussed.A novel technology,bioleaching,used in leaching of vanadium and other valuable metals from stone coal is prospected.
[1]文友.钒的资源应用、开发与展望[J].稀有金属与硬质合金,1996,5(1):51-54.
[2]全国各省矿产资源储量简表.截至2006年底.2007.
[3]Moskalyk R R,Alfantazi A M.Processing of Vanadium:A Review[J].Mineral Engineering,2003,16(9):793-805.
[4]朱燕,贺慧琴,邓方,等.钒渣中钒的浸出特性[J].环境科学与技术,2006,29(12):16-17.
[5]孙中良.矿产一般工业要求汇编,DZ/T0200—2002.2006:38.
[6]王忠,王军.国内外五氧化二钒市场状况与分析[J].稀有金属与硬质合金,2007,16(2):47-51.
[7]张建廷,陈碧.攀西钒钛磁铁矿主要元素赋存状态及回收利用[J].矿产保护与利用,2008(5):38-41.
[8]李光强,张鹏科,朱诚意,等.用碳热还原法从含钒钢渣回收含钒生铁[J].四川冶金,2005,27(5):61-64.
[9]漆明鉴.从石煤中提钒现状及前景[J].湿法冶金,1999,18(4):1-10.
[10]肖文丁.广西上林石煤的矿物学和湿法提钒研究[J].有色金属,2007,59(3):85-90.
[11]林海玲,范必威.方山口石煤提钒焙烧相变机理的研究[J].稀有金属,2001,25(4):273-277.
[12]陈双莉,史玲,谢建宏,等.陕西某碳酸盐型钒矿提钒研究[J].辽宁化工,2007,36(10):696-699.
[13]陈铁军,邱冠周,朱德庆.石煤提钒焙烧过程钒的价态变化及氧化动力学[J].矿冶工程,2008,28(3):64-67.
[14]赖第华,李坤林.石煤脱炭焙烧水浸提钒工艺研究[J].四川有色金属,2009,(2):33-36.
[15]史玲,王娟,谢建宏.钠化法提钒工艺研究[J].矿冶工程,2008,28(1):58-61.
[16]戴文灿,朱柒金,陈庆邦,等.石煤提钒综合利用新工艺的研究[J].有色金属,2000,(3):15-17.
[17]谭爱华.某石煤钒矿空白焙烧-碱浸提钒工艺研究[J].湖南有色冶金,2008,24(1):24-26.
[18]余志伟,邢丽华.含钒石墨尾矿提钒技术研究[J].金属矿山,2008,(8):142-144.
[19]刘万里,王学文,王明玉,等.石煤提钒低温硫酸化焙烧矿物分解工艺[J].中国有色金属学报,2009,19(5):943-948.
[20]向小艳,王明玉,肖连生,等.石煤酸浸提钒工艺研究[J].稀有金属和硬质合金,2007,35(3):10-13.
[21]郑祥明,田学达,张小云,等.湿法提取石煤中钒的新工艺研究[J].湘潭大学自然科学学报,2003,25(1):43-45.
[22]曹耀华,杨绍文,高照国,等.某钒矿酸法提钒新工艺试验研究[J].矿产综合利用,2008(5):3-6.
[23]李廷,魏昶,李存兄,等.低碳石煤加压浸取提钒新工艺研究[J].铀矿冶,2008,27(3):129-133.
[24]Li M T,Wei C,Fan G,et al.Extraction of Vanadium From Black Shale Using Pressure Acid Leaching[J].Hy-drometallurgy,2009,98(3):308-313.
[25]曹来宗,刘代俊,高丽花,等.亚熔盐法浸取钒的实验研究[J].钢铁钒钛,2008,29(2):1-4.
[26]Dopson M,L vgren L.,Bostr m D.Silicate Mineral Disso-lutionin the Presence of Acidophilic Microorganisms:Im-plicationfor Heap Bioleaching[J].Hydrometallurgy,2009,96(4):288-293.
[27]Bell J ML,Philp J C,Kuyukina MS,et al.Methods Evalu-ating Vanadium Tolerance in Bacteria Isolated from Crude Oil Contaminated Land[J].Journal of Microbiological Methods,2004,58(1):87-100.
[28]Katarina B,Hans H K,Olle H.Reduction of Vanadium(V)WithAcidithiobacillus ferrooxidansandAcidithio-bacillus thiooxidans[J].Bioresource Technology,2004,92(1):93-96.
[29]Pradhan D,Mishra D,Kim DJ,et al.Bioleaching Kinetics and Multivariate Analysis of Spent Petroleum Catalyst Dissolution Using Two Acidophiles[J].Journal of Hazard-ous Materials,2010,175(1/3):267-273.
[30]Mishra D,Kim DJ,Ralph D E,et al.Bioleaching of Vana-dium Rich Spent Refinery Catalysts Using Sulfur Oxidizing Lithotrophs[J].Hydrometallurgy,2007,88(1):202-209.
[31]Mishra D,Kim DJ,Chaudhury G R,et al.Dissolution Ki-netics of Spent Petroleum Catalyst Using Two Different Acidophiles[J].Hydrometallurgy,2009,99(3/4):157-162.
[32]Aung K M M,Ting Y P.Bioleaching of Spent Fluid Cata-lytic Cracking Catalyst UsingAspergillusniger[J].Jour-nal of Biotechnology,2005,116(2):159-170.
基本信息:
DOI:10.13355/j.cnki.sfyj.2010.04.013
中图分类号:TF841.3
引用信息:
[1]蒋凯琦,郭朝晖,肖细元.中国钒矿资源的区域分布与石煤中钒的提取工艺[J].湿法冶金,2010,29(04):216-219+224.DOI:10.13355/j.cnki.sfyj.2010.04.013.
基金信息: