蔡宗英;张莉霞;

• 1:北京科技大学理化系
• 2:首钢技术研究院 北京100083
• 3:军械工程学院
• 4:河北石家庄050003

摘要(Abstract)：

介绍了电化学制备陶瓷的各方法原理,主要包括阴极电沉积和阳极电沉积陶瓷薄膜2种方式。其中阴极电沉积陶瓷原理基于胶体化学的DLVO理论,包括电泳沉积(EPD)和电解沉积(ELD)2种方式;而阳极电沉积原理基于阳极氧化理论,主要介绍了阳极氧化、微弧氧化和水热电化学技术。阳极电沉积需要消耗阳极材料,但其陶瓷和基体结合力相对较强。

关键词(KeyWords)： 陶瓷;电化学;沉积

Abstract:

Keywords:

基金项目(Foundation):

作者(Authors): 蔡宗英;张莉霞;

DOI: 10.13355/j.cnki.sfyj.2005.04.001

参考文献(References)：

• [1]范志国,王飙.金属基陶瓷复合材料的制备方法及其新进展[J].昆明理工大学(理工版),2003,28(4):49-53.
• [2]熊金平,叶皓,赵景茂,等.氧化物薄膜电化学沉积的研究进展[J].材料保护,2002,35(2):4-6.
• [3]张建民,冯祖德,林建昌,等.电沉积功能陶瓷技术[J].功能材料,1998,29(2):128-131.
• [4]熊金平,叶皓,赵景茂,等.氧化物薄膜电化学沉积的研究进展[J].材料保护,2002,35(2):4-6.
• [5]Zhitomirsky I.Cathodic Electrodeposition of Ceramic and Ora-ganoceramic Materials.Fundamental Aspects[J].Advances inColloid and Interface Science,2002,97(1/3):279-317.
• [6]石雷,刘维民.电化学沉积法制备纳米金属多层膜的研究进展[J].润滑与密封,2003,27(5):78-80.
• [7]赵中伟,李洪桂,孙培梅,等.电化学沉积生物陶瓷新方法[J].稀有金属与硬质合金,2002,30(1):6-8.
• [8]Espitia-Cabrera I,Orozco-Hernández H,Torres-Sánchez R,etal.Synthesis of Nanostructured Zirconia Electro-depositedFilms on AISI 316L Stainless Steel and Its Behaviour inCorrosion Resistance Assessment[J].Materials Letters,2003,58(1/2):191-195.
• [9]曹建春,周晓龙,郭忠诚,等.不锈钢表面ZrO2涂层的制备及性能[J].机械工程材料,2004,28(8):29-31.
• [10]Kalakodimi Rajendra Prasad,Kazumichi Koga,Norio Miura.Electrochemical Deposition of Nanostructured Indium Oxide:High-performance Electrode Material for Redox Supercapaci-tors[J].Chemisty of Materials,2004,16(10):1845-1847.
• [11]游常,江东亮,谭寿洪,等.电泳沉积法制备碳化钛膜的研究[J].陶瓷学报,2001,22(3):125-128.
• [12]张道礼,胡云春,黎步银,等.电泳沉积原理及其在陶瓷制备中的应用[J].现代技术陶瓷,1999,21(4):22-25.
• [13]帕奇克.尼科森,帕瑟.撒卡,桑瓦.达塔.用电泳沉积法制作陶瓷叠层复合材料[J].江西建材,1997,16(2):44-47.
• [14]Lyklema J.Principles of Stability of Lyophobic Colloidalin Non-aqueous Media.Adv.Colloid Interface Sci,1968,(2):65-114.
• [15]张建民,杨长春,石秋芝,等.电泳沉积功能陶瓷涂层技术[J].中国陶瓷,2000,36(6):36-40.
• [16]陈宗淇,戴闽光.胶体化学[M].北京:高等教育出版社,1984:272-285.
• [17]周祖康,顾惕人,马季铭.胶体化学基础[M].北京:北京大学出版社,1987:271-279.
• [18]D J肖.胶体与表面化学导论[M].张中路,张仁佑.北京:化学工业出版社,1989:198-227.
• [19]Koelmans H,Overbeek J Th G.Stability and Electro-phoretic Deposition of Suspensions in Non-aqueousMedia,Discuss.Faraday Society.1954(18):52-62.
• [20]Zhitomirsky I.New Development in Electrolytic of CeramicFilms[J].American Ceramic Society Bulletin,2000,79(9):57-63.
• [21]Ji-Ho Park,Doung-Youn Lee,Keun-Taek Oh,et al.BioactiveCalcium Phosphate Coating on Sodium Hydroxide-pretreatedTitanium Substrate by Electrodeposition[J].Journal of theAmerican Ceramic Society,2004,87(9):1792-1794.
• [22]张建民,魏爱卿.两步电化学沉积技术制备功能陶瓷/金属复合镀层[J].化学研究,2003,14(4):1-3,6.
• [23]Matsumoto Y,Morikawa T,Adachi H,et al.A NewPreparation Method of Barium Titanate Perovskite FilmUsing Electrochemical Reduction[J].Materials ResearchBulletin,1992,27(11):1319-1327.
• [24]Zhitomirsky I.Electrolytic Deposition of Oxide Films inthe Presence of Hydrogen Peroxide[J].Journal of theCeramic Society,1999,19(15):2581-2587.
• [25]Wu Chu-Tsun,Lu Fu-Hsing.Electrochemical Deposition ofBarium Titanate Films Using a Wide Electrolytic VoltageRange[J].Thin Solid Films,2001,398-399(11):621-625.
• [26]刘东阳,吴建青,饶平根,等.阳极氧化制备纳米孔径的多孔Al2O3膜[J].中国陶瓷,2004,40(1):45-48.
• [27]Lu Fu-Hsing,Wu Chu-Tsun,Hung Chuen-Ya.BariumTitanate Films Synthesized by an Anodic Oxidation-basedElectrochemical Method[J].Surface and Technology,2002,153(2/3):276-283.
• [28]毕剑,肖定全,高道江,等.电化学制备Ba1-xSrxWO4薄膜的工艺研究及分析表征[J].功能材料,2004,35(2):225-230.
• [29]毕剑,赖欣,高道江,等.电化学沉积CaWO4薄膜及表征[J].四川师范大学学报,2003,26(5):513-516.
• [30]刘凤岭,骆更新,毛立信.微弧氧化与材料表面陶瓷化[J].材料保护,1998,31(3):22-24.
• [31]薛文斌,邓志威,来永春,等.有色金属表面微弧氧化技术评述[J].金属热处理,2000,42(1):1-3.
• [32]Van T B,Brown S D,Wirtz G P.Mechanism of AnodicSpark Eeposition[J].American Ceramic Society Bulletin,1977,56(6):563-566.
• [33]Krysmann W,Kurze P,Dittrich K H.Process Characteristicsand Parameters of Anodic Oxidation by Spark Discharge(ANOF)[J].Crystal Research Technology,1984,19(7):973-979.
• [34]高道江,肖定全,张文,等.水热电化学技术及其在陶瓷薄膜制备中的应用[J].功能材料,2002,33(3):240-242.
• [35]Tomás Vargas,Hugo Díaz.Hydrothermal-electrochemicalFormation of BaTiO3Films:Electrochemical Characteriza-tion of the Early Stages of Growth[J].Journal of theAmerican Ceramic Society,1997,80(1):213-218.
• [36]Koji Kajiyoshi,Kunisaburo Tomono,Yukio Hamaji,YoruKasanami.Short-circuit Diffusion of Ba,Sr,and ODuring ATiO3(A=Ba,Sr)Thin Films Growth by theHydrothermal-electrochemical Method[J].Journal of theAmerican Ceramic Society,1995,78(6):1521-1531.
• [37]Masahiro Yoshimura,Wojciech L Suchanel,Tomoaki Watan-abe.In Situ Fabrication of SrTiO3-BaTiO3Layered ThinFilms by Hydrothermal-electrochemical Technique[J].Jour-nal of the European Ceramic Society,1999,19(6/7):1353-1359.