丝瓜络的改性及用其从海水中吸附铀试验研究Modification of Loofah and Adsorption Uranium From Seawater
李子明;陈树森;宿延涛;勾阳飞;宋艳;常华;王凤菊;吴浩天;
摘要(Abstract):
研究了通过化学引发将丝瓜络纤维骨架接枝丙烯腈单体,再用盐酸羟胺进行化学改性,制备偕亚胺二肟改性丝瓜络(LC-AO)。利用红外光谱、元素分析、热重分析等手段确定了LC-AO的化学结构,并考察其从模拟海水中吸附与解吸铀的性能。结果表明:LC-AO对铀质量浓度为3 mg/L的模拟海水中铀的吸附量为18.1 mg/g,吸附过程符合准二级动力学模型。
关键词(KeyWords): 海水;丝瓜络;偕亚胺二肟;改性;丙烯腈;吸附;铀
基金项目(Foundation):
作者(Authors): 李子明;陈树森;宿延涛;勾阳飞;宋艳;常华;王凤菊;吴浩天;
DOI: 10.13355/j.cnki.sfyj.2022.03.007
参考文献(References):
- [1] WEI L,GAO X,FAN T,et al.Engineering robust metal-phenolic network membranes for uranium extraction from seawater[J].Energy & Environmental Science,2019,12(2):607-614.
- [2] WANG Y,LIN Z,ZHANG H,et al.Anti-bacterial and super-hydrophilic bamboo charcoal with amidoxime modified for efficient and selective uranium extraction from seawater[J].Journal of Colloid and Interface Science,2021,598(40):455-463.
- [3] MEGAN K,CAMDEN H,CARROLL T G,et al.Redox-switchable carboranes for uranium capture and release[J].Nature,2020,577:652-655.
- [4] XU X,XU L,AO J,et al.Ultrahigh and economical uranium extraction from seawater via interconnected open-pore architecture poly(amidoxime) fiber[J].Journal of Materials Chemistry:A,2020,8(42).DOI:10.1039/D0TA07180C.
- [5] WANG Z,MENG Q,MA R,et al.Constructing an ion pathway for uranium extraction from seawater[J].Chem,2020,6(7):1683-1691.
- [6] TANG N,LIANG J,NIU C G,et al.Amidoxime-based materials for uranium recovery and removal[J].Journal of Materials Chemistry:A,2020,8(3):7588-7625.
- [7] ABNEY C W,MAYES R T,SAITO T,et al.Materials for the recovery of uranium from seawater[J].Chemical Reviews,2017,117(23):13935-14013.
- [8] 李昊,文君,汪小琳.中国海水提铀研究进展[J].科学通报,2018,63:481-494.
- [9] 陈树森,任宇,丁海云,等.海水提铀的研究进展[J].原子能科学技术,2015,49(3):415-423.
- [10] PICARD M,BAELDEN C,YOU W U,et al.Extraction of uranium from seawater:design and testing of a symbiotic system[J].Nuclear Technology,2017,188(2):200-217.
- [11] 熊洁,文君,胡胜,等.中国海水提铀研究进展[J].核化学与放射化学,2015,37(5):257-265.
- [12] WANG D,SONG J,WEN J,et al.Significantly enhanced uranium extraction from seawater with mass produced fully amidoximated nanofiber adsorbent[J].Advanced Energy Materials,2018,8(33).DOI:10.1002/aenm.201802607.
- [13] YUAN Y,YU Q,WEN J,et al.Ultrafast and highly selective uranium extraction from seawater by hydrogel-like spidroin-based protein fiber[J].Angewandte Chemie International Edition,2019,131(34).DOI:10.1002/ange.20190 6191.
- [14] YAN B,MA C,GAO J,et al.An lon-crossiinked supramolecular hydrogel for ultrahigh and fast uranium recovery from seawater[J].Advanced Materials,2020,32(10).DOI:10.1002/adma.201906615.
- [15] YU Q,YUAN Y,FENG L,et al.Spidroin-inspired,high-strength,loofah-shaped protein fiber for capturing uranium from seawater[J].Angewandte Chemie International Edition,2020,59(37).DOI:10.1002/anie.202007383.
- [16] YUAN Y,LIU T,XIAO J,et al.DNA nano-pocket for ultra-selective uranyl extraction from seawater[J].Nature Communications,2020,11(1).DOI:10.1038/s41467-020-19419-z.
- [17] XU X,ZHANG H,AO J,et al.3D hierarchical porous amidoxime fibers speed up uranium extraction from seawater[J].Energy & Environmental Science,2019,12(6):1979-1988.
- [18] PAN H B,WAI C M,KUO L J,et al.A highly efficient uranium grabber derived from acrylic fiber for extracting uranium from seawater[J].Dalton Transactions,2020,49(9):2803-2810.
- [19] DAVIES R V,KENNEDY J,MCILROY R W,et al.Extraction of uranium from sea water[J].Nature,1964,203:1110-1115.
- [20] ELOY F,LENAERS R.The chemistry of amidoximes and related compounds[J].Chemical Reviews,1962,62(2):155-183.
- [21] DAS S,BROWN S,MAYES R T,et al.Novel poly(imide dioxime) sorbents:development and testing for enhanced extraction of uranium from natural seawater[J].Chemical Engineering Journal,2016,298(15):125-135.
- [22] ZHANG A,ASAKURA T,UCHIYAMA G.The adsorption mechanism of uranium(Ⅵ) from seawater on a macroporous fibrous polymeric adsorbent containing amidoxime chelating functional group[J].Reactive & Functional Polymers,2003,57(1):67-76.
- [23] KATRAGADDA S,GESSER H D,CHOW A,et al.The extraction of uranium by amidoximated orlon[J].Talanta,1997,45(2):257-263.
- [24] KANG S O,VUKOVIC S,CUSTELCEAN R,et al.Cyclic imide dioximes:formation and hydrolytic stability[J].Industrial & Engineering Chemistry Research,2012,51(19):6619-6624.
- [25] VUKOVIC S,HAY B P.De novo structure-based design of bis-amidoxime uranophiles[J].Inorganic Chemistry,2013,52(13):7805-7810.
- [26] LI S,J LI,MA N,et al.Super-compression-resistant multiwalled carbon nanotube/nickel-coated carbonized loofah fiber/polyether ether ketone composite with excellent electromagnetic shielding performance[J].ACS Sustainable Chemistry & Engineering,2019,7(16):13970-13980.
- [27] HUANG J,ZENG J,WANG H,et al.Biomimetic fabrication of highly ordered laminae-trestle-laminae structured copper aero-sponge[J].Nanoscale,2020,12(16):8982-8990.
- [28] YAKOUT S M,RIZK M A.Adsorption of uranium by low-cost adsorbent derived from agricultural wastes in multi-component system[J].Desalination and Water Treatment,2015,53(7):1917-1922.