载镁牛粪生物炭对磷酸盐的吸附性能及机制Adsorption Performance and Mechanism of Mg-loaded Cow Dung Biochar for Phosphate
孔令营;尹志轩;何德明;刘长青;张国闽;
摘要(Abstract):
研究了对牛粪生物炭进行载镁改性并用于从废水中吸附去除磷酸盐,考察了磷酸盐初始质量浓度、生物炭投加量和溶液初始pH对磷酸盐吸附去除效果的影响;通过多种吸附模型对试验数据进行拟合并分析吸附机制。结果表明:牛粪生物炭通过载镁改性可显著提高吸附性能,其对磷酸盐的吸附量约为改性前的22倍;吸附效果受磷酸盐初始质量浓度和改性生物炭用量影响较大,可在较宽pH范围内保持较高吸附量;准二级动力学模型和Langmuir等温吸附模型可以更好地描述吸附过程,吸附过程主要为单分子层化学吸附;吸附过程吸热,升高温度有利于提高吸附效果。
关键词(KeyWords): 牛粪;生物炭;载镁;改性;磷酸盐;吸附;废水
基金项目(Foundation): 国家重点研发计划项目(2020YFD1100303);; 山东省重大科技创新工程项目(2018YFJH0902);; 山东省自然科学基金资助项目(ZR2019BEE028);; 青岛理工大学环境科学与工程一流学科开放课题(QUTSEME201929)
作者(Authors): 孔令营;尹志轩;何德明;刘长青;张国闽;
DOI: 10.13355/j.cnki.sfyj.2022.03.010
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