有机物还原氧化锰工艺研究进展Research Advances of Reduction of Manganese Oxide Ore by Organic Matter
卢友志;卢国贤;明宪权;李维健;袁爱群;黄增尉;周泽广;马少妹;
摘要(Abstract):
用低品位氧化锰矿石制备金属锰是获取锰的主要方法,而有机物还原浸出锰是重要的工艺手段之一。综述了近年来国内外以有机物为还原剂还原氧化锰的研究状况,指出了现有工艺存在的问题和发展方向,旨在为软锰矿有机还原工艺的深入研究和工业化应用提供参考。
关键词(KeyWords): 有机物;氧化锰矿石;还原;浸出;锰
基金项目(Foundation): 广西高校锰深加工校企科技创新平台项目(GJXQ2013);; 广西民族大学研究生教育创新计划项目(gxun-chx2014092)
作者(Authors): 卢友志;卢国贤;明宪权;李维健;袁爱群;黄增尉;周泽广;马少妹;
DOI: 10.13355/j.cnki.sfyj.2015.01.01
参考文献(References):
- [1]李同庆.低品位软锰矿还原工艺技术与研究进展[J].中国锰业,2008,26(2):4-14.
- [2]耿叶静,刘静,曹向会,等.用富镁低品位锰矿石制备硫酸锰的试验研究[J].湿法冶金,2012,31(6):372-379.
- [3]阳启华,张昭.SO2浸出软锰矿过程中抑制连二硫酸锰生成的研究[J].湿法冶金,2012,31(3):144-148.
- [4]蔡振勇,易清风,刘汉勇,等.废铁屑还原软锰矿制备高纯硫酸锰工艺研究[J].中国锰业,2011,29(3):28-31.
- [5]彭荣华,李晓湘.用钛白副产的硫酸亚铁浸锰制备高纯二氧化锰[J].无机盐工业,2006,38(12):48-50.
- [6]El-Hazek M N,Lasheen T A,Helal A S.Reductive Leaching of Manganese From Low Grade Sinai Ore in HC1 Using H2O2 as Reductant[J].Hydrometallurgy,2006,84(12):187-191.
- [7]Ismail A A,Ali E A,Ibrahim,et al.A Comparative Study on Acid Leaching of Low Grade Manganese Ore Using Some Industrial Wastes as Reductants[J].The Canadian Journal of Chemical Engineering,2004,82(6):1296-1300.
- [8]黄齐茂,王春平,徐旺生,等.木屑还原低品位软锰矿制备硫酸锰工艺研究[J].无机盐工业,2010,42(2):49-51.
- [9]Song J J,Zhu G C,Zhang P,et al.Reduction of Low-grade Manganese Oxide Ore by Biomass Roasting[J].Acta Metall Sin,2010,23(3):223-229.
- [10]Hariprasad D,Dash B,Ghosh M K,et al.Leaching of Manganese Ores Using Sawdust as A Reductant[J].Minerals Engineering,2007,20(14):1293-1295.
- [11]杨幼平,黄可龙.植物粉料-硫酸法直接浸出软锰矿的实践[J].中国矿业,2001,10(5):54-56.
- [12]邓益强.植物粉料焙烧软锰矿制备硫酸锰的新工艺研究[J].材料研究与应用,2008(2):55-58.
- [13]粟海峰,孙英云,文衍宣,等.废糖蜜还原浸出低品位软锰矿[J].过程工程学报,2007,7(6):1089-1093.
- [14]孙英云.废糖蜜还原浸出低品位软锰矿的工艺及动力学研究[D].南宁:广西大学,2008.
- [15]Lasheen T A,El-Hazek M N,Helal A S,et al.Recovery of Manganese Using Molasses as Reductant in Nitric Acid Solution[J].Int J Miner Process,2009,92(3):109-114.
- [16]Lasheen T A,El-Hazek M N,Helal A S.Kinetics of Reductive Leaching of Manganese Oxide Ore With Molasses in Nitric Acid Solution[J].Int J Miner Process,2009,98(3):314-317.
- [17]粟海峰,蒋娜,陈超,等.木薯酒糟还原浸出低品位软锰矿工艺研究[J].无机盐工业,2011,43(9):46-48.
- [18]粟海峰,蒋娜,黎铉海,等.木薯酒精废水还原浸出氧化锰矿的研究[C]//2012年全国冶金物理化学学术会议专辑:下册,2012.
- [19]黎克純.软锰矿降解糖蜜酒精废液并同时浸出锰的过程研究[D].南宁:广西大学,2008.
- [20]崔畅,张永忠,李文滨.蛋白黑素的研究进展[J].食品科学,2007,28(8):517-520.
- [21]张吉,周文红,刘慧霞.甘蔗糖蜜酒精废液中总黄酮含量的测定[J].广西轻工业,2005(2):18-20.
- [22]粟海锋,崔嵬,文衍宣.芦丁还原浸出低品位软锰矿的研究[J].广西大学学报(自然科学版),2010,35(3):373-377.
- [23]蔡振勇,易清风,宋伟.甘蔗汁还原软锰矿制备高纯碳酸锰工艺研究[J].中国锰业,2011,29(4):13-16.
- [24]叶显甲.甘蔗渣焙烧还原软锰矿-硫酸浸出锰的工艺研究[D].南宁:广西大学,2012.
- [25]崔益顺.蔗渣还原硫酸浸取低品位软锰矿工艺研究[J].无机盐工业,2013,45(10):45-47.
- [26]Cheng Z,Zhu G C,Zhao Y N.Study in Reduction-roast Leaching Manganese From Low-grade Manganese Dioxide Ores Using Cornstalk as Reductant[J].Hydrometallurgy,2009,96(1/2):176-179.
- [27]Tian X,Wen X X,Yang C,et al.Reductive Leaching of Manganese From Low-grade Manganese Dioxide Ores Using Corncob as Reductant in Sulfuric Acid Solution[J].Hydrometallurgy,2010,100(3/4):157-160.
- [28]黎春杏,黄艳芳,商渊婷,等.榕树叶化学成分的预试验[J].微量元素与健康研究,2014,31(2):34-35.
- [29]Hariprasad D,Ghosh M K,Anand S.Dried Leaves-Novel Reductant for Acid Leaching of Manganese Ore[J].Transactions of The Indian Institute of Metals,2009,62(6):551-554.
- [30]杨明平,宋和付,李国斌.米糠-硫酸直接浸锰工艺条件研究[J].无机盐工业,2005,37(2):30-32.
- [31]Tang Q,Zhong H,Wang S,et al.Reductive Leaching of Manganese Oxide Ores Using Waste Rea-leaf as Reductant in Sulfuric Acid Solution[C]//第七届国际分离科学与技术会议论文集,2013.
- [32]钟琼.柚子皮还原浸出低品位软锰矿工艺研究[J].矿冶工程,2013,33(4):101-103.
- [33]Feng Y,Cai Z,Li H,et al.Response Surface Optimization of Fluidized Roasting Reduction of Low-grade Pyrolusite Coupling With Pretreatment of Stone Coal[J].J Min Metall Sect B-Metall,2013,49(1):33-41.
- [34]叶显甲,苏静,粟海峰,等.甘蔗渣焙烧软锰矿的热重红外联用(TG-FTIR)分析[J].广西大学学报(自然科学版),2012,37(3):440-444.
- [35]Trifoni M,Veglini F,Taglieri G,et al.Acid Leaching Process by Using Glucose as Reducing Agent:A Comparision Among The Efficiency of Different Kinds of Manganiferous Ores[J].Minerals Engineering,2000,13(2):217-221.
- [36]Veglio F,Trifoni M,Toro L,et al.Leaching of Manganiferous Ores by Glucose in A Sulfuric Acid Solution:Kinetic Modeling and Related Statistical Analysis[J].Ind Eng Chem Res,2001,40(18):3895-3901.
- [37]Veglio F,Toro L.Fractional Factorial Experiments in The Development of Manganese Dioxide Leaching by Sucrose in Sulphuric Acid Solutions[J].Hydrometallurgy,1994,36(2):215-230.
- [38]Beolchini F,Papinii M P,Toro L,et al.Acid Leaching of Manganiferousores by Sucrose:Kinetic Modelling and Related Statistical Analysis[J].Minerals Engineering,2001,14(5):175-184.
- [39]Furlani G,Moscardini E,Pagnanelli F,et al.Recovery of Manganese From Zinc Alkaline Batteries by Reductive Acid Leaching Using Carbohydrates as Reductant[J].Hydrometallurgy,2009,99(1):115-118.
- [40]张亚辉,栾和林,姚文,等.苯酚或苯胺还原浸出大洋锰结核的机理研究与验证[J].矿冶,1997,6(1):51-57.
- [41]Khan Z,Kumar Parveen,Kabir-ud-Din.Kinetics of The Reduction of Water-soluble Colloidal MnO2 by Ascorbic Acid[J].Journal of Colloid and Interface Science,2005,29(1):184-189.
- [42]Kabir-ud-Din,Shakeel Iqubal S M.Kinetics of the Reduction of Water Soluble Colloidal MnO2by Mandelic Acid in The Absence and Presence of Non_Ionic Surfactant Triton X-100[J].2010,72(2):195-204.
- [43]Kabir-ud-Din,Shakeel Iqubal S M,Zaheer Khan.Reduction of Soluble Colloidal MnO2by DL-malic Acid in The Absence and Presence of Nonionic TritonX-100[J].Colloid and Polymer Science,2005,283(5):504-511.
- [44]Das A P,Swain S,Panda S,et al.Reductive Acid Leaching of Low Grade Manganese Ores[J].Geomaterials,2012,2(4):70-72.
- [45]田学达.软锰矿无煤还原制备硫酸锰溶液的方法:中国,200310110442.3[P].2005-04-27.
- [46]Momade F W Y,Momade Z G.Reductive Leaching of Manganese Oxide Ore in Aqueous Methanol Sulphuric Acid Medium[J].Hydrometallurgy,1999,51(1):103-113.
- [47]Hariprasad D,Mohapatra M,Anand S.Sulphuric Acid Leaching of Low/medium Grade Manganese Ores Using a Novel Nitrogeneous Reductant NH3NH2HSO4[J].J Min Metall Sect B-Metall,2013,49(1):97-106.