用高比表面针铁矿吸附氟的试验研究Adsorption of Fluoride Using Goethite With High Specific Surface
龙伟;杨建广;唐施阳;南天翔;唐朝波;曾伟志;
摘要(Abstract):
研究了采用剪切强化法制备高比表面积针铁矿,借助X-射线衍射仪、扫描电子显微镜、氮气物理性吸附等手段表征针铁矿的微观结构,通过单因素试验考察了溶液初始pH、吸附时间、温度、初始F-质量浓度、针铁矿用量、共存阴离子等对针铁矿吸附F-质量浓度、针铁矿用量、共存阴离子等对针铁矿吸附F-的影响。结果表明:所制备的针铁矿比表面积高达206.91 m-的影响。结果表明:所制备的针铁矿比表面积高达206.91 m2/g,对F2/g,对F-有很强的吸附能力;在初始pH=4、温度25℃、针铁矿用量10 g/L条件下,对F-有很强的吸附能力;在初始pH=4、温度25℃、针铁矿用量10 g/L条件下,对F-质量浓度100 mg/L的溶液吸附处理2 h,其对F-质量浓度100 mg/L的溶液吸附处理2 h,其对F-吸附率达92.2%,吸附量为9.22 mg/g;溶液中Cl-吸附率达92.2%,吸附量为9.22 mg/g;溶液中Cl-和NO-和NO-_3的存在对吸附影响不大,而SO_4-_3的存在对吸附影响不大,而SO_4(2-)会通过竞争作用抑制针铁矿对F(2-)会通过竞争作用抑制针铁矿对F-的吸附。
关键词(KeyWords): 剪切强化;高比表面积;针铁矿;氟;吸附
基金项目(Foundation): 国家重点研发专项课题(2018YFC1900403);; 中南大学中央高校基本科研业务费专项资金资助项目(2020zzts480)
作者(Authors): 龙伟;杨建广;唐施阳;南天翔;唐朝波;曾伟志;
DOI: 10.13355/j.cnki.sfyj.2022.01.012
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