石墨烯气凝胶材料的合成与应用研究现状Current Status of Synthesis and Application of Graphene Aerogels
蔡之望;刘峙嵘;
摘要(Abstract):
石墨烯以其高比表面积、良好的导电性和热稳定性等优点被广泛应用于电化学、催化、吸附等领域,同时也延伸出许多相关材料,石墨烯气凝胶就是其中之一。综合介绍了4种石墨烯气凝胶的合成方法,阐述了相关方面的应用研究进展。
关键词(KeyWords): 氧化石墨烯;石墨烯气凝胶;合成方法;应用
基金项目(Foundation): 国家自然科学基金资助项目(11375043);; 江西省科技支撑计划项目(20151BBG70011);; 省部共建核资源与环境国家重点实验室培育基地自主基金资助项目(Z1504)
作者(Authors): 蔡之望;刘峙嵘;
DOI: 10.13355/j.cnki.sfyj.2017.06.001
参考文献(References):
- [1]NOVOSELOV K S A,GEIM A K,MOROZOV S V,et al.Two-dimensional gas of massless dirac fermions in graphene[J].Nature,2005,438(7065):197-200.
- [2]WANG F,WANG Y,ZHAN W,et al.Facile synthesis of ultralight graphene aerogels with super absorption capability for organic solvents and strain-sensitive electrical conductivity[J].Chemical Engineering Journal,2017,320:539-548.
- [3]LI Y,ZHANG R,TIAN X,et al.Facile synthesis of Fe3O4,nanoparticles decorated on 3Dgraphene aerogels as broadspectrum sorbents for water treatment[J].Applied Surface Science,2016,369:11-18.
- [4]YANG M Q,ZHANG N,WANG Y,et al.Metal-free,robust,and regenerable 3Dgraphene organics aerogel with high and stable photosensitization efficiency[J].Journal of Catalysis,2017,346(4):21-29.
- [5]LI F,XIE L,SUN G,et al.Regulating pore structure of carbon aerogels by graphene oxide as shape-directing'agent[J].Microporous&Mesoporous Materials,2017,240:145-148.
- [6]ZANG P,GAO S,DANG L,et al.Green synthesis of holey graphene sheets and their assembly into aerogel with improved ion transport property[J].Electrochimica Acta,2016,212:171-178.
- [7]LIU X,YU Y,NIU Y,et al.Cobalt nanoparticle decorated graphene aerogel for efficient oxygen reduction reaction electrocatalysis[J].International Journal of Hydrogen Energy,2017,42(9):5930-5937.
- [8]YU M,LI J,WANG L.KOH-activated carbon aerogels derived from sodium carboxymethyl cellulose for high-performance supercapacitors and dye adsorption[J].Chemical Engineering Journal,2017,310:300-306.
- [9]WAN C,LI J.Graphene oxide/cellulose aerogels nanocomposite:preparation,pyrolysis,and application for electromagnetic interference shielding[J].Carbohydrate Polymers,2016,150:172-179.
- [10]XIANG Y,LIU L,LI T,et al.Compressible,amphiphilic graphene-based aerogel using a molecular glue to link graphene sheets and coated-polymer layers[J].Materials&Design,2016,110:839-848.
- [11]FAN Y,MA W,HAN D,et al.Convenient recycling of 3D AgX/graphene aerogels(X=Br,Cl)for efficient photocatalytic degradation of water pollutants[J].Advanced Materials,2015,27(25):3767-3773.
- [12]LI R,YANG T,LI Z,et al.Synthesis of palladium@gold nanoalloys/nitrogen and sulphur-functionalized multiple graphene aerogel for electrochemical detection of dopamine[J].Analytica Chimica Acta,2017,954:43-51.
- [13]SHINKAI T,SUGIYAMA K,ITO K,et al.Nanoporous fabrication of block copolymers via carbon dioxide swelling:difference between CO2-swollen and nanoporous block copolymers[J].Polymer,2016,100:19-27.
- [14]KOSTOGLOU N,CONSTANTINIDES G,CHARALAMBOPOULOU G,et al.Nanoporous spongy graphene:potential applications for hydrogen adsorption and selective gas separation[J].Thin Solid Films,2015,596:242-249.
- [15]HOU Z,JIN Y,XIN X,et al.Hierarchically porous nitrogen-doped graphene aerogels as efficient metal-free oxygen reduction catalysts[J].Journal of Colloid&Interface Science,2017,488(8):317-321.
- [16]胡涵.石墨烯气凝胶的控制制备、改性及性能研究[D].大连:大连理工大学,2014.
- [17]LIM M B,HU M,MANANDHAR S,et al.Ultrafast solgel synthesis of graphene aerogel materials[J].Carbon,2015,95:616-624.
- [18]LI R,LIU L,LI Z,et al.Graphene micro-aerogel based voltammetric sensing of p-acetamidophenol[J].Microchimica Acta,2017,184(5):1417-1426
- [19]MA L,SU L,ZHANG J,et al.A controllable morphology GO/PANI/metal hydroxide composite for supercapacitor[J].Journal of Electroanalytical Chemistry,2016,777:75-84.
- [20]NORALIAN Z,GASHTI M P,EBRAHIMI I.Fabrication of a multifunctional graphene/polyvinylphosphonic acid/cotton nanocomposite via facile spray layer-by-layer assembly[J].Rsc Advances,2016,6(28):23288-23299.
- [21]KOSTOGLOU N,TZITZIOS V,KONTOS A G,et al.Synthesis of nanoporous graphene oxide adsorbents by freeze-drying or microwave radiation:characterization and hydrogen storage properties[J].International Journal of Hydrogen Energy,2015,40(21):6844-6852.
- [22]HE Y,LI J,LI L,et al.Gamma-ray irradiation-induced reduction and self-assembly of graphene oxide into threedimensional graphene aerogel[J].Materials Letters,2016,177:76-79.
- [23]SHI Y,XIONG D,LI J,et al.In situ reduction of graphene oxide nanosheets in poly(vinyl alcohol)hydrogel byγ-ray irradiation and its influence on mechanical and tribological properties[J].Journal of Physical Chemistry:C,2016,120(34):19442-19453.
- [24]LUO K,LI J,LI L,et al.A facile method for preparing 3D graphene/Ag aerogel via gamma-ray irradiation[J].Fullerenes Nanotubes&Carbon Nanostructures,2016,24(11):720-724.
- [25]WANG H,TENG K,CHEN C,et al.Conductivity and electromagnetic interference shielding of graphene-based architectures using MWCNTs as free radical scavenger in gammairradiation[J].Materials Letters,2016,186:78-81.
- [26]CHI C,XU H,ZHANG K,et al.3Dhierarchical porous graphene aerogels for highly improved adsorption and recycled capacity[J].Materials Science&Engineering:B,2015,194:62-67.
- [27]NGUYEN D D,TAI N H,LEE S B,et al.Superhydrophobic and superoleophilic properties of graphene-based sponges fabricated using a facile dip coating method[J].Energy&Environmental Science,2012,5(7):7908-7912.
- [28]DAI J,HUANG T,TIAN S Q,et al.High structure stability and outstanding adsorption performance of graphene oxide aerogel supported by polyvinyl alcohol for waste water treatment[J].Materials&Design,2016,107:187-197.
- [29]MAO X,YANG W,HE X,et al.The preparation and characteristic of poly(3,4-ethylenedioxythiophene)/reduced graphene oxide nanocomposite and its application for supercapacitor electrode[J].Materials Science&Engineering:B,2017,216:16-22.
- [30]陈静.石墨烯气凝胶及薄膜的制备与性能研究[D].北京:北京化工大学,2015.
- [31]REDDY D A,CHOI J,LEE S,et al.Self-assembled macro porous ZnS-graphene aerogels for photocatalytic degradation of contaminants in water[J].Rsc Advances,2015,5(24):18342-18351.
- [32]REDDY D A,CHOI J,LEE S,et al.Green synthesis of AgI nanoparticle functionalized reduced graphene oxide aerogels with enhanced catalytic performance and facile recycling[J].Rsc Advances,2015,5(83):67394-67404.
- [33]CHOI J,REDDY D A,ISLAM M J,et al.Self-assembly of CeO2,nanostructures/reduced graphene oxide composite aerogels for efficient photocatalytic degradation of organic pollutants in water[J].Journal of Alloys&Compounds,2016,688:527-536.
- [34]ZHANG Z,ZHAI S,WANG M,et al.Photocatalytic degradation of rhodamine B by using a nanocomposite of cuprous oxide,three-dimensional reduced graphene oxide,and nanochitosan prepared via one-pot synthesis[J].Journal of Alloys&Compounds,2015,659:101-111.
- [35]MAHDAVI H,KAHRIZ P K,GHOLIPOUR-RANJBAR H,et al.Synthesis and performance study of amino functionalized graphene aerogel grafted with polyaniline nanofibers as an efficient supercapacitor material[J].Journal of Materials Science Materials in Electronics,2017,28(5):4295-4305.
- [36]CAI Z X,SONG X H,CHEN Y Y,et al.3D nitrogendoped graphene aerogel:a low-cost,facile prepared direct electrode for H2O2sensing[J].Sensors&Actuators B:Chemical,2016,222:567-573.
- [37]TRAN D N H,KABIRI S,WANG L,et al.Engineered graphene nanoparticle aerogel composites for efficient removal of phosphate from water[J].Journal of Materials Chemistry:A,2015,3(13):6844-6852.
- [38]CHEN L,FENG S,ZHAO D,et al.Efficient sorption and reduction of U(Ⅵ)on zero-valent iron-polyaniline-graphene aerogel ternary composite[J].Journal of Colloid&Interface Science,2017,490:197-206.
- [39]CHEN M,ZHENG L,LI J,et al.The extraction of uranium using graphene aerogel loading organic solution[J].Talanta,2017,166:284-291.
- [40]HONG J Y,SOHN E H,PARK S,et al.Highly-efficient and recyclable oil absorbing performance of functionalized graphene aerogel[J].Chemical Engineering Journal,2015,269:229-235.
- [41]REN R P,LI W,LYUY K.A robust,superhydrophobic graphene aerogel as a recyclable sorbent for oils and organic solvents at various temperatures[J].Journal of Colloid&Interface Science,2017,500:63-68.
- [42]LI J,WANG F,LIU C Y.Tri-isocyanate reinforced graphene aerogel and its use for crude oil adsorption[J].Journal of Colloid&Interface Science,2012,382(1):13-16.
- [43]WAN Y J,ZHU P L,YU S H,et al.Ultralight,super-elastic and volume-preserving cellulose fiber/graphene aerogel for high-performance electromagnetic interference shielding[J].Carbon,2017,115:629-639.