用绿矾从氧化锌中氧压浸出锌并同步分离铁Oxygen Pressure Leaching of Zn From Zinc Oxide Ore Using FeSO_4·7H_2O and Synchronous Separation of Fe
张爽;李杨;冯好;冯伟光;张华;倪红卫;
摘要(Abstract):
研究了以绿矾(FeSO_4·7H_2O)为浸出剂,采用氧压浸出法从氧化锌矿物中选择性浸出锌,考察了绿矾用量、温度、氧压和反应时间对锌浸出率和溶液中铁沉淀率的影响。结果表明:绿矾用量增加、温度升高、氧压加大和浸出时间延长均有利于锌浸出率提高;在n(FeSO_4·7H_2O)/n(ZnO)=1.1/1、温度150℃、氧压1.5 MPa、反应时间3 h条件下进行浸出,锌浸出率达98.75%,铁沉淀率为99.79%;相同条件下浸出异极矿,锌浸出率达96%,铁和硅沉淀率分别为99.28%和79.10%。用此工艺处理氧化锌矿物,可实现锌的高效浸出和脉石元素的同步分离,有效减少后续除杂工序,也避免废酸对环境的污染。
关键词(KeyWords): 氧化锌;绿矾;氧压浸出;锌;铁;分离
基金项目(Foundation): 国家重点研发计划项目(2018YFC1900602-1);; 钢铁冶金与资源利用教育部重点实验室开放基金资助项目(FMRUlab-20-2)
作者(Authors): 张爽;李杨;冯好;冯伟光;张华;倪红卫;
DOI: 10.13355/j.cnki.sfyj.2022.03.002
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